Chemical product and company identification product name. The process comprises producing diacetone alcohol from acetone in the presence of a solid basic catalyst comprising at least i a metal hydroxide selected among the hydroxides of alkali metals and the hydroxides of alkaline earth metals and ii a binder, and is characterized by using as the solid basic. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Diacetone alcohol definition of diacetone alcohol by. Therefore, the reaction needs a certain amount of heat to decompose the hatom from the isopropyl alcohol. Diacetone alcohol market global industry analysis, size and. Diacetone alcohol market research report forecast to 2023. The production volume of diacetone alcohol in japan is 3,236 tonnesyear in 1995.
D174 casno 123422 synonyms diacetone alcohol recommended use laboratory chemicals. Diacetone alcohol manufacturers prasol chemicals pvt ltd. Diacetone alcohol is mainly used as a solvent in industrial and professional applications in coatings, cleaning, oil and gas filed drilling, lubricants, metal working fluids, polymer processing and water treatment. Cd has several advantages over conventional fixedbed reactors since acetone conversions which exceed the equilibrium limit can be obtained, and no cooling of the acetone feed is required. Process analysis for the production of diacetone alcohol via. Europe is a significant region in the global diacetone alcohol market. Experimental data for the production of diacetone alcohol daa with catalytic distillation cd are presented and discussed. Us2879298a us662323a us66232357a us2879298a us 2879298 a us2879298 a us 2879298a us 662323 a us662323 a us 662323a us 66232357 a us66232357 a us 66232357a us 2879298 a us2879298 a us 2879298a authority us united states prior art keywords acetone alumina activated alumina catalyst production prior art date 19570529 legal status. Roles of acetone and diacetone alcohol in coordination and. Diacetone alcohol and fumarates supporting information. We search the world and bring only the highest quality materials to customers throughout australia, new zealand, malaysia and the united states of america.
The production volume of diacetone alcohol in japan is 3,236 tonnesyear in past years. Diacetone alcohol, fumarates, ethylene glycol, and glycerol were purchased from aladdin industrial inc. Diacetone alcohol definition is a liquid keto alcohol ch3coch2cohch32 made usually by alkaline condensation of acetone and used chiefly as a solvent as in lacquer formulations and in hydraulic brake fluids. Uses advised against food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet 2. Diacetone alcohol material safety data sheet cas no 12342. Simultaneous production of diacetone alcohol and mesityl. Diacetone alcohol daa diacetone alcohol daa is a clear, colorless liquid ketonealcohol. Wear goggles and selfcontained breathing apparatus. Nov 26, 2017 i prepare diacetone alcohol from acetone using barium hydroxide as a catalyst. View products detecting gaseous diacetone alcohol tvoc 2 fixed pid detector tvoc 2 is a fixed pid detector for continuous volatile organic compound voc monitoring with leading pid sensor technology and ultimate resistance to humidity and contamination. Mixtures of hydrogen peroxide and 1phenyl2methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, chem. Wo2004101485a1 process for producing diacetone alcohol. Diacetone alcohol is a chemical compound with the formula ch 3 c och 2 c oh ch 3 2, sometimes called daa.
Diacetone alcohol, having hydroxyl and carbonyl group in the same molecule is used as a chemical intermediate. We use finest quality chemical compounds, sourced from certified vendors to formulate the chemicals. Items available from stock in japan will be delivered in 12 weeks. Volume 62, issues 1820, septemberoctober 2007, pages 55675574. Choline chloride and formic acid were supplied by acros organics. The principal end uses of daa are in industrial coatings, household cleaners, inks, paints, paint removers, paint thinners, pharmaceutical preparations, sealants, primer and pesticides. Identification of the substancemixture and of the companyundertaking 1. Propylene glycol monomethyl ether acetate, 1methoxy2propyl acetate dangerous goods class 3 subsidiary risk none. Safety data sheet creation date 11may2010 revision date 29jul2019 revision number 1 1.
I prepare diacetone alcohol from acetone using barium hydroxide as a catalyst. Diacetone alcohol appears as a clear colorless liquid with a pleasant odor. This liquid is a common synthetic intermediate used for the preparation of other compounds, and is also used as a solvent. Annex vi of directive 67548eec through the 31st atp. Request pdf process analysis for the production of diacetone alcohol via catalytic distillation a threephase nonequilibrium model developed recently in. Please note that we cannot offer bulk quantities for some. Uses advised against food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. An alternative route toward cyclohexanebased plasticizers using diacetone alcohol and fumarates as the starting materials is developed. It is known to produce aldol condensation products from carbonyl compounds, in particular diacetone alcohol from. Key players several manufacturers of diacetone alcohols are focusing on an organic growth strategy. Department of chemical engineering, indian institute of technology, bombay, powai, mumbai 400 076, india abstract dimerization of acetone ac yields diacetone alcohol daa, which on further. Author links open overlay panel suman thotla vishal agarwal sanjay m. Having established the production of 2methyl2,4pentandiol compound 2, we envisioned that acidcatalyzed dehydration of compound 2 could lead to the formation of 1,3diene, which easily reacted with fumarate to a.
Table 20142019 global diacetone alcoho daa key vendors production share list figure 20142019 global diacetone alcoho daa capacity production and growth rate table 20142019 global diacetone alcoho daa key vendors production value m usd list figure 20142019 global diacetone alcoho daa production value m usd and growth rate. Roles of acetone and diacetone alcohol in coordination and dissociation reactions of uranyl complexes. Diacetone alcohol is an organic compound with the formula ch 3 c och 2 c oh ch 3 2, sometimes called daa. Daa is produced by selective aldol condensation of acetone. First identified by heintz, one standard laboratory preparation of daa entails the ba oh 2. Diacetone alcohol daa cas 123422 arkema innovative. With ketone and chemical properties of tertiary alcohols, and alkali or heated to above decomposition, 2 molecular acetone diacetone alcohol diacetone alcohol use as a high boiling point solvents. Simultaneous production of diacetone alcohol and mesityl oxide from acetone using reactive distillation suman thotla, vishal agarwal, sanjay m. Simultaneous production of diacetone alcohol and mesityl oxide from acetone using reactive distillation. Diacetone alcohol is exempted from the requirement of a tolerance when used as a deactivator or a solvent for formulations used before crop emerges from the soil in accordance with good agricultural practice as inert or occasionally active ingredients in pesticide formulations applied to growing crops only.
The only acute inhalation toxicity data available on which to base an idlh for diacetone alcohol is the statement by patty 1963 that animals exposed for 1 to 3 hours to 2,100 ppm exhibited restlessness, irritation of the membranes, excitement, and later somnolence gross as cited by lehmann and flury 1943. Material safety data sheet diacetone alcohol msds section 1. Diacetone alcohol or daa cas 123422 from arkema is a highpurity oxygenated solvent derived from acetone which is colorless, odorless and has a low evaporation rate. Redox is a leading distributor of chemicals and ingredients, active in more than 1,000 specialty and commercial products. The industrial production of 2eho comprises three units. Owing to the fact that acetone is miscible with water, and virtually all organic solvents, it serves as an important solvent in its own right, typically the solvent of choice for cleaning purposes in the laboratory. Diacetone alcohol is used in purification processes for resins and waxes. Our company has marked a global presence in the domain by manufacturing and supplying diacetone alcohol. Diacetone alcohol daa is used as an industrial solvent for nitrocellulose, cellulose acetate, celluloid, pigments, waxes, fats, and oils, and in antifreeze and brake fluid acgih, 1991. Diacetone 4hydroxy4methyl2pentanone tyranton avoid contact with liquid. It is used for paints and coatings, organic peroxides, textiles and leather, chemical synthesis and cleaning.
These two residual impurities are present in commercial grade acetone at trace levels. Identification product name diacetone alcohol cat no. Diacetone alcohol is more suitable for use in applications as a component of gravure printing inks, with proving favorable flow and leveling characteristics. The production of diacetone alcohol with catalytic. Methods s52 allyl alcohol, s55 diacetone alcohol, s54 cyclohexanol, s58 isoamyl alcohol and s60 methyl isobutyl carbinol were issued on january 17, 1975 3, and validated using 10l air samples of atmospheres generated in dry air by calibrated syringe drive from the pure substances 1. Dec 03, 2012 roles of acetone and diacetone alcohol in coordination and dissociation reactions of uranyl complexes. Moreover, the raw material is isopropyl alcohol and water. Over 90% of the diacetone alcohol produced is used as a coatings solvent.
The product is interesting because it is both a ketone and an alcohol. The process comprises producing diacetone alcohol from acetone in the presence of a solid basic catalyst comprising at least i a metal hydroxide selected among the hydroxides of alkali metals and the hydroxides of alkaline earth metals and ii a binder, and is characterized by using as. It is an industrially important compound which is mainly used as a solvent in purification processes. Production of 1,2cyclohexanedicarboxylates from diacetone. It accounted for a considerable market share of 18%, as of 2016. This colorless liquid is a common synthetic intermediate used for the preparation of other compounds, and is also used as a solvent. Diacetone alcohol skin deep cosmetics database ewg. For the same, manufacturer are expanding their production capacity in order to enhance their footprint in regional as well as global market.
Diacetone alcohol 123422 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. It is miscible with the most common organic solvents and with water. Diacetone alcohol daa and mesityl oxide mo are industrially useful products derived from acetone. Daa is used as a chemical intermediate in the preparation of. The toxicological tests indicate that the assynthesized di2ethylhexyl 3,5dimethylcyclohexane1,2dicarboxylate can serve as a safe plasticizer for pvc materials. Wear suitable protective equipment during handling. Request pdf process analysis for the production of diacetone alcohol via catalytic distillation a threephase nonequilibrium model developed recently in our laboratory was used to provide the. It is found in a number of consumer products such as adhesives, inks, paints, household cleaners and agrochemicals. Diacetone alcohol market global industry analysis, size.
Page 1 of 7 msds diacetone alcohol material safety data sheet msds diacetone alcohol 1. Seaborg center, lawrence berkeley national laboratory, berkeley, california 94720, united. Diacetone alcohol is a betahydroxy ketone formed by hydroxylation of 4methylpentan2one at the 4position. Pdf simultaneous production of diacetone alcohol and. Diacetone alcohol daa cautionary response information common synonyms watery liquid colorless to light yellow mild, pleasant odor floats and mixes with water. It is a colorless and limpid liquid, noncorrosive, with a characteristic pleasant smell. A process for diacetone alcohol production in which a longterm operation is possible. Trace level determination of mesityl oxide and diacetone. Diacetonealcoholgeneral, process, applications, patent. Diacetone alcohol 123 42 2 204 626 7 99 min additional information. Hydrogenation of diacetone alcohol to 2methyl2,4pentanediol diacetone alcohol compound 1, the selfaldol product of acetone, was first hydrogenated to 2methyl2,4pentanediol compound 2 over raney ni fig. Acetone production 129 the factory is designed theoretically with a low cost based on the calculations presented in the results section. Process analysis for the production of diacetone alcohol.
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